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16 Common Refrigerants‘ Features

Table of Contents

Refrigerant is directly related to the refrigeration effect of refrigeration equipment even personal safety, so you should know these common refrigerants’ knowledge.

R22

R22 refrigerant is used in household air conditioner, central air conditioner, mobile air conditioner, heat pump water heater, dehumidifier, refrigerated dryer, cold room, food refrigeration equipment, marine refrigeration equipment, industrial refrigeration, commercial refrigeration, refrigeration condensing unit, supermarket display cabinets and other refrigeration equipment.

Notice: Currently R22 refrigerant has been banned in most countries and regions!

ItemDescription
NameMonochlorodifluoromethane, or Freon R22
AbbreviationR22, HCFC-22
ClassificationPure substance
Chemical formulaCHClF2
Molecular weight86.5
Molar mass86.5g/mol
Triple point temperature-157℃
Standard boiling point-40.82℃
Critical temperature96℃
Critical pressure5MPa (absolute pressure)
Critical density0.524g/cm3
Eccentricity factor0.22kJ (kg*℃)
Liquid relative density1.177 (20/4℃)
Vapor relative density (air=1)4.82

R23

R23 is a widely used ultra-low temperature refrigerant, such as environmental test chamber and equipment, freeze dryer, ultra-low temperature refrigerator or freezer, blood bank refrigerator, biochemical test chamber and other deep-freezing equipment.

It also used as a gas fire extinguishing agent, which is cleanliness, low toxicity and good fire extinguishing effect.

ItemDescription
Namefluoroform
AbbreviationR23
Chemical formulaCHF3
Molar mass86.5g/mol
Triple point temperature-157℃
Standard boiling point-82.1℃
Critical temperature25.9℃
Critical pressure4.84MPa (absolute pressure)
Critical volume133ml/mole
CAS Number75-46-7
ODP0
GWP1200
Evaporation potential at boiling point240kJ/kg
Specific heat1.55kJ/kg·℃

R32

R32 is a new type eco-friendly refrigerant. It doesn’t contain chlorine and therefore has no destructive effect on ozone.

However, it is flammable and explosive.

It is one of the substitutes for R22 and R410A refrigerants.

ItemDescription
Namedifluoromethane
AbbreviationR32
Chemical formulaCH2F2
Molecular weight52
Standard boiling point-53℃
Critical temperature78℃
Critical pressure5.8MPa (absolute pressure)
Critical density0.430g/cm3
CAS Number75-10-5
ODP0
GWP0.11
Evaporation potential at boiling point390 kJ/kg
Specific heat2.35 kJ/kg·℃

R134a

R134a, as one most widely used medium and low temperature refrigerant, is a very effective and safe alternative to R12.

ItemDescription
Nametetrafluoroethane
AbbreviationR134a
Chemical formulaC2H2F4
Molecular weight52
Standard boiling point-26.1℃
Critical temperature101.1℃
Critical pressure4066.6KPa
Critical density0.512g/cm3
CAS Number811-97-2
ODP1300
GWP0.29
Evaporation potential at boiling point216kJ/kg
Specific heat1.51kJ/kg·℃

R404a

Composition: R125, R134a, R143a. It’s one most widely used medium and low temperature refrigerant, commonly used in cold storage, food freezing equipment, marine refrigeration equipment, industrial low temperature refrigeration, commercial low temperature refrigeration, transportation refrigeration equipment (refrigerated trucks, etc.), refrigeration condensing unit, supermarket display cabinets and other refrigeration equipment.

ItemDescription
NameMixed refrigerant (R125, R134a, R143a)
AbbreviationR404a
Chemical formulaHFC-404A
Molecular weight97.6
Molar mass97.6g/mol
Critical temperature72℃
Critical pressure3.7 MPa (absolute pressure)
Critical density0.4842g/cm3
CAS Number354-33-6/811-97-2/420-46-2
Liquid density (25℃)1.045g/cm3
Boiling point (101.3KPa)-46.1℃
Specific heat (25℃) Kj/(kg.k)1.54
Isobaric steam specific heat (30℃,101.3kPa)0.21
ODP0
GWP3850

R404 Refrigerant

R290

R290 is a hydrocarbon refrigerant, which is flammable and explosive! It has no damage to the ozone layer and has a very small greenhouse effect, and it’s one of the most eco-friendly refrigerant.

R290 used to replace R22 and R502 refrigerants in low-temperature refrigeration equipment. Since R290 refrigerant is flammable and explosive, so usually only used in low-temperature refrigeration equipment with small refrigerant charge.

R290 is compatible with traditional lubricants, and used for central air conditioner, heat pump air conditioner, household air conditioner and other small refrigeration equipment.

ItemDescription
Namepropane
AbbreviationR290
Chemical formulaCH3CH2CH3、C3H8
Molecular weight44
Standard boiling point-42.2℃
Critical temperature96.7℃
Critical pressure4.25MPa (absolute pressure)
ODP0
GWP20

R600a

R600a is a hydrocarbon refrigerant with excellent performance, flammable and explosive, doesn’t damage ozone layer, no greenhouse effect.

It has large latent heat of evaporation and strong cooling capacity, good flow performance, low delivery pressure, low power consumption, and slow load temperature recovery. It is compatible with various compressor lubricants.

ItemDescription
Nameisobutane
AbbreviationR600a
Chemical formulaCH(CH3)3、CH3-CH(CH3)-CH3
Molecular weight58
Standard boiling point-11.7℃
Critical temperature135℃
Critical pressure3.6 MPa (absolute pressure)
Critical density226kg/m3
Vapor density (air = 1)2.01
CAS Number75-28-5
ODP0
GWP0

R433b

R433b refrigerant is a hydrocarbon refrigerant with small molecular weight, good flow performance, low delivery pressure, reduced compressor load, and extended compressor service life.

ItemDescription
NameMixed refrigerant (Propylene, Propane)
AbbreviationR433b
Chemical formulaR433B,HC-433B
Molecular weight44
Molar mass44g/mol
Critical temperature96℃
Critical pressure4.27MPa
Critical density221
CAS Number74-98-6/115-07-1
ODP0
GWP3

R436a

R436a is a hydrocarbon refrigerant that doesn’t damage the ozone layer and has no greenhouse effect.

Its thermal performance is similar to R134a.

ItemDescription
NameMixed refrigerant (R32,R125, R134a)
AbbreviationR436a
Chemical formulaHC-436A
Molecular weight38
Molar mass38g/mol
Critical temperature33.4℃
Critical pressure4.27 MPa (absolute pressure)
Critical density0.17g/cm3
CAS Number74-98-6/75-28-5
ODP0
GWP3

R407c

R407c is an eco-friendly medium and high temperature refrigerant mixed with R32, R125 and R134a, which used in various air-conditioning systems and non-centrifugal refrigeration systems.

Mainly used in household air conditioner, small and medium-sized commercial air conditioner, mobile air conditioner (car air conditioner, etc.), dehumidifiers, refrigerated dryers, marine refrigeration equipment, industrial refrigeration and other refrigeration equipment.

ItemDescription
NameMixed refrigerant (R125, R32, R134a)
AbbreviationR407c
Chemical formulaHFC-407C
Molecular weight86.2
Molar mass86.2g/mol
Critical temperature85.8℃
Critical pressure4.6 MPa (absolute pressure)
Critical density0.4753 g/cm3
CAS Number75-10-5/354-33-6/811-97-2
Liquid density (25℃)1.136kg/L
Boiling point (101.3KPa)-43.6℃
Saturated vapor pressure (25℃)1174kPa
Latent heat of evaporation250kJ/kg
ODP0
GWP1.526

R410a

R410A is a new type eco-friendly refrigerant that doesn’t damage the ozone layer. Its working pressure is 1.6 times that of R22.

It has high refrigeration efficiency and used as a substitute for R22.

R410a Refrigerant

Since R410a and R22 have different pressures (R410a pressure is much higher than R22), and the compressor oil is also different, so we forbidden to use R410a for after-sales maintenance of refrigeration equipment initially installed with R22 refrigerant.

ItemDescription
NameMixed refrigerant (R125 50% + R32 50%)
AbbreviationR410a
Chemical formulaHFC-410A
Molecular weight72.6
Molar mass72.6g/mol
Critical temperature70.5℃
Critical pressure4.8 MPa (absolute pressure)
Critical density0.4339 g/cm3
CAS Number75-10-5/354-33-6
Liquid density (25℃)1.136kg/L
Boiling point -51.6℃
Saturated liquid density (30℃)1.038 g/cm3
Liquid specific heat (30℃)1.78 [KJ/(Kg·℃)]
ODP0
GWP2090

CO2

CO2 refrigerant is a natural substance. It has no destructive effect on the atmospheric ozone layer, can reduce the global greenhouse effect, doesn’t need recycle, can greatly reduce the cost of refrigerant replacement, save energy, fundamentally solve the problem of compound pollution to the environment, and has good economic efficiency.

In addition, CO2 is safe, non-toxic, non-flammable, good thermal stability. CO2 has thermal properties that are compatible with refrigeration cycles and equipment.

It has large refrigeration capacity. The unit refrigeration capacity at 0°C is 5~8 times higher than that of conventional refrigerants.

ItemDescription
NameCO2
ClassificationPure substance, natural refrigerant
Molecular weight44.01
Molar mass44.01 g/mol
Standard boiling point-40.82℃
Critical temperature31.1℃
Critical pressure7.38 MPa (absolute pressure)
Critical density0.468 g/cm³
Boiling Point-78.5℃
Saturated Liquid Density (at 30℃)1.177 (20/4℃)
Liquid Specific Heat (at 30℃):0.85 KJ/(Kg·℃)
ODP0
GWP1
CAS Number124-38-9
Evaporation Potential at Boiling Point345.5 KJ/Kg

R507

R507 refrigerant doesn’t contain CFC and HCFC that damage the ozone layer. It’s a main low-temperature eco-friendly refrigerant recognized and recommended by most countries in the world.

R507 widely used in cold storage, food freezing equipment, marine refrigeration equipment, industrial low-temperature refrigeration, commercial low-temperature refrigeration, refrigerated trucks, refrigeration condensing units, supermarket display cabinets and other refrigeration equipment.

ItemDescription
NameR507
ClassificationMixture, blended refrigerant
Molecular weight98.9
Molar mass98.9 g/mol
Critical temperature70.9℃
Critical pressure3.79 MPa (absolute pressure)
Critical density0.485 g/cm³
Boiling Point-47.1℃
Saturated Liquid Density (at 30℃)1.032 g/cm³
Liquid Specific Heat (at 30℃):1.53 KJ/(Kg·℃)
ODP0
GWP1
CAS Number354-33-6/75-10-5
Evaporation Potential at Boiling Point200.5 KJ/Kg

R717

R717 (ammonia) refrigerant is easy to make, cheap, doesn’t damage the ozone layer, no greenhouse effect. Ammonia vapor is colorless and has a strong irritating odor.

Ammonia is highly toxic to the human body and can cause frostbite when ammonia liquid splashes onto the skin.
Ammonia isn’t easy to burn at room temperature, but when heated to 350°C, it decomposes into nitrogen and hydrogen. When hydrogen mixes with oxygen in the air, it will explode.

ItemDescription
NameR717
ClassificationPure substance, natural refrigerant
Molecular weight17.03
Molar mass17.03 g/mol
Critical temperature132.4℃
Critical pressure11.3 MPa (absolute pressure)
Critical density0.235 g/cm³
Boiling Point-33.3℃
Saturated Liquid Density (at 30℃)0.682 g/cm³
Liquid Specific Heat (at 30℃):4.6 KJ/(Kg·℃)
ODP0
GWP0
CAS Number7664-41-7
Evaporation Potential at Boiling Point1368 KJ/Kg

R449a

R449a is alternative to R404a refrigerant and widely used in medium and low temperature refrigeration applications such as supermarket refrigerated display cabinets, refrigerated transportation, low-temperature cold storage, industrial and commercial refrigeration systems.

ItemDescription
NameR449A
ClassificationMixture, blended refrigerant
Molecular weight87.2
Molar mass87.2 g/mol
Critical temperature81.5℃
Critical pressure4.49 MPa (absolute pressure)
Critical density0.484 g/cm³
Boiling Point-46.3℃
Saturated Liquid Density (at 30℃)1.07 g/cm³
Liquid Specific Heat (at 30℃):1.53 KJ/(Kg·℃)
ODP0
GWP1397
CAS Number1234yf/125/134a/32
Evaporation Potential at Boiling Point250 KJ/Kg

R513a

R513a mainly used in medium and low temperature refrigeration equipment, such as commercial refrigeration display cabinets, chillers, supermarket refrigeration equipment, automotive air-conditioning systems and other industrial refrigeration applications.

ItemDescription
NameR513A
ClassificationMixture, blended refrigerant
Molecular weight102.0
Molar mass102.0 g/mol
Critical temperature95.0℃
Critical pressure3.63 MPa (absolute pressure)
Critical density0.491 g/cm³
Boiling Point-29.2℃
Saturated Liquid Density (at 30℃)1.12 g/cm³
Liquid Specific Heat (at 30℃):1.75 KJ/(Kg·℃)
ODP0
GWP573
CAS Number811-97-2/754-12-1
Evaporation Potential at Boiling Point210 KJ/Kg

 

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Vic Cheung

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